The Maximum Hardness Principle and the Composition of Zn(II) and Cd(II) Tetrafluoroborate Complexes with Nitrogen-Containing Organic Bases

被引：0

作者：

A. N. Chebotarev

M. V. Shestakova

V. E. Kuz'min

A. G. Artemenko

机构：

[1] Mechnikov University,

来源：

Russian Journal of Coordination Chemistry | 2005年 / 31卷

关键词：

Nitrogen; Zinc; Physical Chemistry; Cadmium; Inorganic Chemistry;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The hardness/softness parameters of the central complexing ion, the donor nitrogen atom of the ligand, and the coordination bond were calculated for zinc and cadmium tetrafluoroborate complexes with nitrogen-containing organic bases of various composition (both experimentally determined and hypothetical). On the basis of the quantitative estimate of the hard/soft characteristics of the whole series of the coordination compounds considered, it was found that the hardest parameters are inherent in the complexes isolated in a pure state by a preparative method.

引用

页码：619 / 622

页数：3

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