Liquid-liquid equilibrium for the ternary systems of solvents+water+propionic acid at 25 ‡C and atmospheric pressure

被引:0
作者
Jae-Kyung Kim
Dong-Won Park
机构
[1] Dong-A University,Department of Chemical Engineering
来源
Korean Journal of Chemical Engineering | 2005年 / 22卷
关键词
Liquid-Liquid Equilibrium; Ternary; NRTL; UNIQUAC; Propionic Acid;
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学科分类号
摘要
Liquid-liquid equilibrium data for the ternary systems of toluene+water+propionic acid, o-xylene+water +propionic acid, methyl isobutyl ketone+water+propionic acid, ethyl acetate+water+propionic acid, and 1-butanol +water+propionic acid were measured at 25 ‡C and atmospheric pressure. The reliability of the experimental tie-line data was ascertained by means of the Othmer-Tobias, Bachman-Brown, and Hand correlations. For the extraction effectiveness of solvents, the distribution and selectivity curves were plotted. In addition, these experimental tie-line data were also correlated with NRTL and UNIQUAC models.
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页码:256 / 263
页数:7
相关论文
共 37 条
[1]  
Abrams D. S.(1975)Statistical Thermodynamics of Liquid Mixtures: A New Expression for the Excess Gibbs Energy of Partly or Completely Miscible Systems AIChE J. 21 116-116
[2]  
Prausnitz J. M.(1995)Liquid-Liquid Equilibria of the Ternary Mixtures Water+Propanoic Acid+Methyl Ethyl Ketone and Water+Propanoic Acid+Methyl Propyl Ketone J. Chem. Eng. Data 40 225-225
[3]  
Arce A.(1994)Liquid-Liquid Equilibria for the Oleic Acid-Β-Sitosterol-Water System at Elevated Temperatures and Pressures Ind. Eng. Chem. Res. 33 151-151
[4]  
Blanco A.(1948)Distribution in Hydrocarbon Solvent Systems Ind. Eng. Chem. 40 103-103
[5]  
Souza P.(1993)Liquid-Liquid Equilibria of Water+Acetic Acid+Phthalic Esters (Dimethyl Phthalate and Diethyl Phthalate) Ternaries J. Chem. Eng. Data 38 23-23
[6]  
Vidal I.(1996)Liquid-Liquid Equilibria of the Ternary System Water+Acetic Acid+2-Methyl-2-butanol J. Chem. Eng. Data 41 1311-1311
[7]  
Briones J.A.(1997)Liquid-Liquid Equilibria of the Ternary System Water+Acetic Acid+1-Hexanol J. Chem. Eng. Data 42 183-183
[8]  
Mullins J. C.(1930)Dineric Distribution J. Phys. Chem. 34 1961-1961
[9]  
Thies M. C.(1961)Direct Search Solution of Numerical and Statistical Problems J. Assoc. Comput. Mach. 8 212-212
[10]  
Brown T. F.(1993)Extraction Processes for Bioproduct Separation Separ. Sci. Technol. 28 805-805