Improving the efficiency of energy use is of utmost importance in the context of climate change. Indeed, greater efficiency in the end-use of energy will make a significant contribution to lowering primary energy consumption and reducing CO2 and other greenhouse gas emissions. This paper presents an approach that enables a compact liquefied natural gas station to operate without being connected to the public electric grid. It is achieved by using the Boil-off gas generated by the vehicle supply process and feeding it to a generator which, together with a photovoltaic (PV) system, can produce electrical energy. Results from a year of trial operations at the station in Escariz, Portugal, demonstrate that it is possible to recover an average of 8.66 kg of Boil-off gas daily while generating a 345% excess of electrical energy when combined with the PV system, enabling the station to be self-sustainable in terms of electricity. Based on the experimental data and calculation methodology, the project was able to earn an estimated monthly revenue of €176.27 throughout the study period while also preventing the emission of 8549 kg of CO2 equivalent from natural gas combustion in vehicles.