Addition reactions of 1,1,1-trifluoro-4-trimethylstannylbut-3-yn-2-one and 1,1,1-trifluorobut-3-yn-2-one to some tetrahydropyridines. Synthesis of trifluoroacylated polysubstituted tetrahydroazocines

被引：0
作者：
A. B. Koldobskii
E. V. Solodova
V. N. Kalinin
机构：
[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Chemical Bulletin | 2010年 / 59卷
关键词：
trifluoroacetylacetylenes; tetrahydropyridines; [2+2] cycloaddition; ring expansion; tetrahydroazocines;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A reaction of tetrahydropyridines, obtained by the Diels-Alder reaction from α,β-unsat-urated N,N-dimethylhydrazones and methyl acrylate, with acetylenes activated with the trifluoroacetyl group has been studied and found to lead to polysubstituted trifluoroacylated tetrahydroazocines. No cyclobutene intermediates have been detected.
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页码：1010 / 1013
页数：3
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