The Volumetric Study of the Forced Hydrolysis of the Beryllium(II) Cation in the Aqueous Solution

被引：0
作者：
Dmitri A. Rozmanov
Yury V. Sidorov
Kim A. Burkov
机构：
[1] Saint-Petersburg State University,Department of Chemistry
来源：
Journal of Solution Chemistry | 2005年 / 34卷
关键词：
Volume changes; dilatometry; beryllium aquahydroxo complexes; hydrolysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The volume change of the forced hydrolysis of the beryllium cation has been investigated by dilatometry and potentiometry methods. An equilibrium scheme has been proposed and the volume effects of the individual stages have been determined relative to the volume change of the neutralization reaction. It has been shown that the hydrolytic polymerization of the beryllium cation leads to a decrease of the solution volume compared with the neutralization reaction. Such behavior is a unique feature of the beryllium cation.
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页码：1081 / 1090
页数：9
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