Intramolecular spin state switching mechanisms of transition metal complexes

被引：0
作者：
V. I. Minkin
A. G. Starikov
机构：
[1] Southern Federal University,Institute of Physical and Organic Chemistry
[2] Southern Scientific Center,undefined
[3] Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2015年 / 64卷
关键词：
molecular switches; configurational isomerism; valence tautomerism; redoxactive ligands; spin crossover; electromerism; photochromism;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The principal molecular mechanisms that control spin state switching rearrangements of transition metal complexes are considered. A new approach to the structural design of valence tautomeric compounds involving the formation of adducts of four-coordinate metal complexes with bidentate redox-active ligands is proposed. By means of theoretical modeling methods, new molecular systems with photo-switchable magnetic properties based on transition metal complexes with photochromic ligands are suggested.
引用
收藏
页码：475 / 497
页数：22
相关论文
共 321 条
[1]  
Sato O.(2007)undefined Angew. Chem., Int. Ed. 46 2152-undefined
[2]  
Tao J.(2008)undefined Russ. Chem. Bull. (Int. Ed.) 57 687-undefined
[3]  
Zhang Y.(2013)undefined Adv. Mater. 25 378-undefined
[4]  
Minkin V. I.(2010)undefined Adv. Mater. 22 3348-undefined
[5]  
Zhang J.(2013)undefined Adv. Mater. 25 302-undefined
[6]  
Zou Q.(2013)undefined Adv. Mater. 25 331-undefined
[7]  
Tian H.(2014)undefined Chem. Soc. Rev. 43 148-undefined
[8]  
Russew M.-M.(1998)undefined Science 279 44-undefined
[9]  
Hecht S.(2011)undefined Nat. Chem. 3 564-undefined
[10]  
Zheng Y. B.(1996)undefined J. Chem. Phys. 105 11024-undefined
12345678910