Chemical thermodynamics of nickel, copper, and zinc uranyl sulfates

被引：0

作者：

N. V. Karyakin

A. V. Knyazev

S. A. Gavrilova

机构：

[1] Lobachevsky Nizhni Novgorod State U., Nizhni Novgorod

来源：

Radiochemistry | 2003年 / 45卷 / 5期

基金：

俄罗斯基础研究基金会;

关键词：

Zinc; Entropy; Nickel; 5H2O; Enthalpy;

D O I：

10.1023/A:1026211909674

中图分类号：

学科分类号：

摘要：

The standard enthalpies of formation at 298.15 K of crystalline A II[UO2(SO4)2]·5H 2O (AII = Ni, Cu, Zn) were determined by reaction calorimetry. The heat capacities of these compounds in the range 7-300 K were measured by adiabatic vacuum calorimetry, and their thermodynamic functions were calculated. The standard entropies and Gibbs energies of formation of these compounds at 298.15 K were calculated. The standard thermodynamic functions of the synthesis reactions were calculated and discussed.

引用

页码：484 / 487

页数：3

共 12 条

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