Modification of molybdenum disulfide (2H-MoS2) and synthesis of its intercalation compounds

被引：0
|
作者：
A. S. Golub’
D. P. Rupasov
N. D. Lenenko
Yu. N. Novikov
机构：
[1] Russian Academy of Sciences,Nesmeyanov Institute of Organoelement Chemistry
[2] Moscow State University,undefined
来源：
Russian Journal of Inorganic Chemistry | 2010年 / 55卷
关键词：
Molybdenum Disulfide; Interlayer Space; Layered Compound; Diethylamine; Ammonium Cation;
D O I：
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中图分类号：
学科分类号：
摘要：
We have shown that powdered molybdenum disulfide prepared as a result of the exfoliation (singlelayer dispersion) of a crystalline precursor (2H-MoS2) and subsequent precipitation in an acid medium, is capable of forming intercalation compounds in reacting with salts of copper and tetramethylammonium, as well as diethylamine and triethylamine. We consider factors influencing the composition and type of the alternation of guest and host layers in the resulting layered compounds. Relationships between charge transfer to MoS2 layers and the extraordinary reactivity of its modified species are discussed.
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页码：1166 / 1171
页数：5
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