Structure of Cs4(HSO4)3(H2PO4) single crystals

被引：0
|
作者：
I. P. Makarova
V. V. Grebenev
I. I. Vasil’ev
E. V. Dmitricheva
V. A. Komornikov
V. V. Dolbinina
A. S. Mikheikin
机构：
[1] Russian Academy of Sciences,Shubnikov Institute of Crystallography
[2] European Synchrotron Radiation Facility,Swiss–Norwegian Beamlines
[3] Southern Federal University,Faculty of Physics
来源：
Crystallography Reports | 2016年 / 61卷
关键词：
Crystallography Report; Structural Phase Transition; Thermal Vibration; Potassium Atom; High Protonic Conductivity;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Single crystals of Cs4(HSO4)3(H2PO4) are synthesized and studied for the first time. The new compound is found in the course of studies of the phase diagram of the CsHSO4–CsH2PO4–H2O triple system. Data on the atomic crystal structure of single-crystalline and powder specimens, as well as on structural phase transitions, are obtained.
引用
收藏
页码：18 / 23
页数：5
相关论文
共 50 条
  • [21] STRUCTURE OF CS-3(HSO4)(2)(H2PO4) - A NEW COMPOUND WITH A SUPERPROTONIC PHASE-TRANSITION
    HAILE, SM
    KREUER, KD
    MAIER, J
    ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1995, 51 : 680 - 687
  • [22] Proton dynamics in Cs2(HSO4)(H2PO4) studied by 1H NMR
    Hayashi, S
    Mizuno, M
    SOLID STATE IONICS, 2005, 176 (7-8) : 745 - 754
  • [23] Proton-Conducting Composite Materials Based on the Cs6H(HSO4)3(H2PO4)4 Compound
    Komornikov, V. A.
    Grebenev, V. V.
    Timakov, I. S.
    Zainullin, O. B.
    PHYSICS OF THE SOLID STATE, 2019, 61 (12) : 2382 - 2385
  • [24] Cs3（HSO4）2（H2PO4）的制备及其导电性研究
    赵国燕
    郭金福
    卢印
    安阳师范学院学报, 2011, (02) : 107 - 109
  • [25] Proton-Conducting Composite Materials Based on the Cs6H(HSO4)3(H2PO4)4 Compound
    V. A. Komornikov
    V. V. Grebenev
    I. S. Timakov
    O. B. Zainullin
    Physics of the Solid State, 2019, 61 : 2382 - 2385
  • [26] Composite electrolytes Cs3(H2PO4)(HSO4)2/SiO2 with high proton conductivity
    Ponomareva, VG
    Shutova, ES
    SOLID STATE IONICS, 2005, 176 (39-40) : 2905 - 2908
  • [27] Phase transition in a superprotonic conductor Cs2(HSO4)(H2PO4) induced by water vapor
    Takeya, Satoshi
    Hayashi, Shigenobu
    Fujihisa, Hiroshi
    Honda, Kazumasa
    SOLID STATE IONICS, 2006, 177 (15-16) : 1275 - 1279
  • [28] Superprotonic behavior of Cs2(HSO4)(H2PO4) -: a new solid acid in the CsHSO4-CsH2PO4 system
    Chisholm, CRI
    Haile, SM
    SOLID STATE IONICS, 2000, 136 : 229 - 241
  • [29] Structure and vibrational spectrum of β-Cs3(HSO4)2[H2-x(P1-x, Sx)O4] (X∼0.5), a new superprotonic conductor, and a comparison with α-Cs3(HSO4)2(H2PO4)
    Haile, SM
    Calkins, PM
    Boysen, D
    JOURNAL OF SOLID STATE CHEMISTRY, 1998, 139 (02) : 373 - 387
  • [30] Incorporation of ammonium ions in Cs2(HSO4)(H2PO4) confirmed by solid-state NMR
    Hayashi, Shigenobu
    Jimura, Keiko
    SOLID STATE IONICS, 2017, 311 : 83 - 89
12345