Structure of liquid-crystalline phases formed by N-acetyl-L-glutamic acid oligomeric benzyl esters –2H NMR study

被引：0

作者：

A. Yoshino

M. Ishida

H. Yuki

H. Okabayashi

H. Masuda

C. J. O'Connor

机构：

[1] Department of Applied Chemistry Nagoya Institute of Technology Gokiso-cho,

[2] Showa-ku,undefined

[3] Nagoya 466-8555,undefined

[4] Japan,undefined

[5] Department of Chemistry The University of Auckland,undefined

[6] Private Bag 92019,undefined

[7] Auckland,undefined

[8] New Zealand,undefined

来源：

Colloid and Polymer Science | 2001年 / 279卷

关键词：

Key wordsN-Acetyl-L-glutamic acid oligopeptide benzyl esters; 2H NMR; Liquid-crystalline phase;

D O I：

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学科分类号：

摘要：

A series of N-acetyl-L-glutamic acid oligopeptide benzyl esters with exact residue numbers 4, 6, and 12 has been synthesized by a stepwise procedure. For these oligopeptide–dioxane binary systems, the behavior of the liquid-crystalline phases has been examined␣by the use of 2H NMR, and the results indicate that highly ordered aggregates formed by these oligopeptides in dioxane are in an alignment similar to that in a nematic mesophase.

引用

页码：1144 / 1148

页数：4