Separation of Inorganic Anions Using an 18-Crown-6-ether-modified Organic Polymer Monolithic Stationary Phase in Capillary Ion Chromatography

被引：0
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作者：
Kenichi Tsuge
Lee Wah Lim
Toyohide Takeuchi
机构：
[1] Gifu University,Department of Chemistry and Biomolecular Science, Faculty of Engineering
来源：
Analytical Sciences | 2021年 / 37卷
关键词：
Crown ether-bonded stationary phase; inorganic anions; capillary ion chromatography;
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摘要：
In this study, a monolithic organic polymer stationary phase was modified using 18-crown-6-ether for use in capillary ion chromatography. Its use in the separation of inorganic anions was investigated. The monolithic stationary phase was obtained by chemically bonding 2-aminomethyl-18-crown-6-ether to a polymer skeleton comprising glycidyl methacrylate and ethylene glycol dimethacrylate. The optimum level of the loading of 2-aminomethyl-18-crown-6-ether onto the stationary phase was investigated. The resulting stationary phase was used to investigate the influence of the eluent cation, the concentration of the eluent, and the pH of the eluent on the separation of inorganic anions.
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页码：845 / 850
页数：5
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