Hydrophosphination of alkoxyalkenes catalyzed by transition metal complexes

被引:0
作者
M. O. Shulyupin
I. G. Trostyanskaya
M. A. Kazankova
I. P. Beletskaya
机构
[1] Moscow State University,Faculty of Chemistry
来源
Russian Journal of Organic Chemistry | 2006年 / 42卷
关键词
Oxidation; Hydrogen; Ether; Hydrogen Peroxide; Organic Chemistry;
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中图分类号
学科分类号
摘要
Diphenylphosphine adds to alkyl vinyl ethers in the presence of Ni(II) and Pd(II) complexes with a high regioselectivity, leading to exclusive formation of the corresponding Markownikoff adducts which were isolated as 1-alkoxyalkyl(diphenyl)phosphine oxides via oxidation with hydrogen peroxide.
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页码:17 / 22
页数:5
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