Kinetics of the carbomethoxylation of methylacetylene-allene mixtures catalyzed by palladium complexes

被引：0

作者：

G. A. Korneeva

E. M. Karas’kova

M. G. Makarov

E. V. Slivinskii

机构：

[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis

[2] Mendeleev University of Chemical Technology,undefined

来源：

Kinetics and Catalysis | 2005年 / 46卷 / 1期

关键词：

Physical Chemistry; Catalysis; Palladium; Ph3P; Phenanthroline;

D O I：

10.1007/PL00021983

中图分类号：

学科分类号：

摘要：

Pathways leading to the desired product and by-product (copolymer of allene and CO) were determined for the carbomethoxylation of allene—methylacetylene mixtures catalyzed by the PdCl2(Ph3P)2—HCl—ortho—phenanthroline system. Ratios for the rates of these transformations were found. Allene ⇄ methylacetylene isomerization under carbomethoxylation conditions was observed.

引用

页码：43 / 46

页数：3

共 9 条

[1]

Makarova E.M.(2001)undefined Neftekhimiya 41 209-undefined

[2]

Korneeva G.A.(2003)undefined Neftekhimiya 43 23-undefined

[3]

Slivinskii E.V.(undefined)undefined undefined undefined undefined-undefined

[4]

Korneeva G.A.(undefined)undefined undefined undefined undefined-undefined

[5]

Karas’kova E.M.(undefined)undefined undefined undefined undefined-undefined

[6]

Skryleva E.A.(undefined)undefined undefined undefined undefined-undefined

[7]

Voronova Z.D.(undefined)undefined undefined undefined undefined-undefined

[8]

Antipov E.M.(undefined)undefined undefined undefined undefined-undefined

[9]

Slivinskii E.V.(undefined)undefined undefined undefined undefined-undefined

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