Influence of Solvent on the Reaction of Diphenyl Carbonyl Oxide with Benzaldehyde

被引：0

作者：

A.M. Nazarov

G.A. Yamilova

V.D. Komissarov

机构：

[1] RAS,Institute of Organic Chemistry

来源：

Reaction Kinetics and Catalysis Letters | 2000年 / 71卷

关键词：

Carbonyl oxide; benzaldehyde; reactivity; chemiluminescence;

D O I：

暂无

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学科分类号：

摘要：

Influence of the solvent on the relative rate constant for the reaction of benzophenone oxide with benzaldehyde has been studied. The solvent influence can be quantitatively described by the semi-empirical Koppel-Palm equation. It is shown that non-specific solvation due to electrostatic interactions lowers, while polarizability enhances the reactivity of diphenyl carbonyl oxide. The specific solvation affects the reaction mainly through the parameter of electrophilicity by decreasing the carbonyl oxide reactivity.

引用

页码：363 / 368

页数：5