A method for determining the charge state of chromium in Cr-doped Bi12SiO20 and Bi12TiO20 materials

被引:0
作者
A. A. Nechitailov
M. V. Krasin’kova
A. P. Nechitailov
机构
[1] Russian Academy of Sciences (RAS),A. F. Ioffe Physico
[2] Russian National Aluminum-Magnesium Institute (VAMI),Technical Institute
来源
Refractories and Industrial Ceramics | 2004年 / 45卷
关键词
Color; Chromium; Charge State; Acid Medium; Chemical Method;
D O I
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中图分类号
学科分类号
摘要
A chemical method for determination of the charge state of chromium in B2O3-based materials (Bi12SiO20 and Bi12TiO20 single crystals) in a wide Cr concentration range (1 × 10−5 − 2 × 10−2 wt.%)is proposed. The method is based on a color reaction between Cr6+ and diphenylcarbazide in an acid medium.
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页码:428 / 430
页数:2
相关论文
共 26 条
  • [1] Mokrushina E. V.(1996)Effect of a low chromium impurity on properties of photoinduced charger carriers in Bi Optics Comm. 23 592-596
  • [2] Nechitailov A. A.(1979)TiO Optics Comm. 30 203-205
  • [3] Prokofiev V. V.(1982) and Bi J. Phys. Chem. Solids 43 767-769
  • [4] Wardzynski W.(1984)SiO J. Phys. Chem. Solids 45 887-896
  • [5] Lukasiewicz T.(1984) single crystals Ukr. Fiz. Zh. 29 1186-1191
  • [6] Zmija J.(1992)Reversible photochromic effects in doped single crystals of bismuth germanium (BGO) and bismuth silicon (BSO) oxides J. Lumin. 53 524-528
  • [7] Wardzynski W.(1997)Light induced charge transfer processes in Cr-doped Bi Neorg. Mater. 33 574-580
  • [8] Szymczak H.(1985)GeO Zh. Anal. Khim. 40 2007-2012
  • [9] Patau K.(undefined) and Bi undefined undefined undefined-undefined
  • [10] Lukasiewicz T.(undefined)SiO undefined undefined undefined-undefined