Experimental results concerning the role of Pt, Rh, Ba, Ce and Al2O3 on NOx-storage catalyst behaviour

被引：0
作者：
V. Schmeißer
J. de Riva Pérez
U. Tuttlies
G. Eigenberger
机构：
[1] Universität Stuttgart,Institut für Chemische Verfahrenstechnik
来源：
Topics in Catalysis | 2007年 / 42-43卷
关键词：
NSC; NO; reduction; NO; storage; washcoat; kinetic measurement;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
NOx-storage catalysts (NSC) with varied washcoat compositions have been investigated experimentally under lean and rich conditions. Besides the fact that Ba and Rh are essential for NOx-storage and -reduction, it was observed that Ba accelerates the NO-reduction and decreases NO-oxidation kinetics. It also turned out to be the promoting species regarding water gas shift reaction. The results revealed kinetic inhibition effects by CO, C3H6 and NO, being less pronounced with Ba in the washcoat. It is further shown that the cyclic NOx-conversion of the NSC is mainly determined by the processes in the regeneration phase.
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页码：15 / 19
页数：4
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