Binary mixtures of cyclohexanone, 2-butanone, 1,4-dioxane and 1,2-dimethoxyethane

被引:0
|
作者
K. Tamura
T. Yamasawa
机构
[1] Osaka City University,Department of Chemistry, Graduate School of Science
来源
Journal of Thermal Analysis and Calorimetry | 2002年 / 69卷
关键词
excess isentropic and isothermal compressibilities; excess volume and thermal expansion factor; binary mixtures; excess isochoric heat capacity;
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摘要
Densities and sound velocities of binary mixtures of cyclohexanone, 2-butanone, 1,4-dioxane and 1,2-dimethoxyethane were measured at 298.15 K and also the densities at 303.15 K. Excess volumes were determined from densities. Isentropic compressibilities were determined from densities and sound velocities, and excess thermal expansion factors were determined from excess volumes of two temperatures. Excess isothermal compressibilities and excess isochoric heat capacities were then estimated using excess isobaric heat capacities previously reported. Excess volumes and excess isentropic and isothermal compressibilities were negative except for cyclohexanone+1,4-dioxane system.
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页码:849 / 863
页数:14
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