Synthesis, crystal structure and properties of a one-dimensional polymeric copper(II) complex of tetrachlorophthalate

被引：0
|
作者：
Shi-Yao Yang
La-Sheng Long
Zhen-Yi Wu
Meng-Xiong Zhan
Rong-Bin Huang
Lan-Sun Zheng
机构：
[1] Xiamen University,State Key Laboratory for Physical Chemistry of Solid Surfaces
来源：
Transition Metal Chemistry | 2002年 / 27卷
关键词：
Oxidation; Polymer; Copper; Spectroscopy; Physical Chemistry;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The coordination polymer [Cu2L2(H2O)6 · 2(H2O)]n (L = μ-tetrachlorophthalate dianion) has been synthesized and characterized by X-ray crystallography, i.r. spectroscopy, electronic spectroscopy and cyclic voltammetry. The structure of the complex is a one-dimensional zigzag chain. The i.r. spectra reveal that the tetrachlorophthalate groups are bismonodentate ligands, and this is confirmed by the crystal structure determination. Cyclic voltammetry reveals two steps of a quasi-reversible oxidation–reduction processes for the complex.
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页码：546 / 549
页数：3
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