Thin tantalum pentoxide films deposited by photo-induced chemical vapor deposition using an injection liquid source

被引:0
作者
J.-Y. Zhang
I.W. Boyd
M.B. Mooney
P.K. Hurley
J.T. Beechinor
B.J. O’Sullivan
P.V. Kelly
G.M. Crean
J.-P. Senateur
C. Jimenez
M. Paillous
机构
[1] Electronic and Electrical Engineering,
[2] University College London,undefined
[3] Torrington Place,undefined
[4] London WC1E 7JE,undefined
[5] UK,undefined
[6] National Microelectronics Research Centre,undefined
[7] Lee Maltings,undefined
[8] Prospect Row,undefined
[9] Cork,undefined
[10] Ireland,undefined
[11] Institut National Polytechnique de Grenoble,undefined
[12] École Nationale Superieure de Physique de Grenoble – LMGP,undefined
[13] B.P. 46 38402 St. Martin d’Heres,undefined
[14] France,undefined
关键词
PACS: 42.72.+h; 61.80.Ba; 81.60.Cp; 85.50.Na;
D O I
10.1007/PL00021075
中图分类号
学科分类号
摘要
We report the growth of thin tantalum pentoxide films on Si (100) by ultraviolet-assisted injection liquid source (UVILS) chemical vapor deposition (CVD) at low temperatures (200–350 °C). This new technique combines the intense radiation from an excimer lamp (λ=222 nm) with a novel injection liquid source capable of delivering precisely controllable quantities of a liquid metalorganic precursor into the CVD chamber. The composition and optical properties of the oxides were determined using a variety of standard characterization methods. After optimization of the deposition parameters, the best layers were incorporated into simple MOS test structures to enable electrical characterization. Refractive index values of 2.09±0.07, fixed oxide charge content of <5×1010 cm-2, breakdown fields higher than 2 MV/cm and dielectric constant values of 18–24 were readily achievable in the as-deposited films. These properties compare favorably with those for layers prepared by conventional thermal-CVD at significantly higher temperatures of 500 °C.
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页码:647 / 649
页数:2
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