Palladium acetate complexes in the gas phase

被引：0
作者：
I. Ya. Yakushev
A. E. Gekhman
A. P. Klyagina
A. A. Markov
M. N. Vargaftik
I. P. Stolyarov
N. V. Cherkashina
A. B. Kornev
I. I. Moiseev
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Russian Academy of Sciences,The Institute of Problems of Chemical Physics
来源：
Russian Journal of Coordination Chemistry | 2016年 / 42卷
关键词：
palladium; coordination compounds; carboxylates; mass spectrometry; quantum chemical calculations;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
New palladium acetate complexes, Pd2(OOCMe)4+, Pd2(OOCMe)3+, Pd2(OOCMe)2+, and Pd2(OOCMe)+ were detected in the thermal decomposition products of trans-Pd(Py)2(OOCMe)2 by mass spectrometry with direct ion source. The geometric and electronic structures of the Pd2(μ-OOCMe)4+ cation and the Pd2(OOCMe)4 molecule were established by quantum chemical calculations (DFT with the PBE1PBE hybrid exchange correlation potential in the 6-31G*/SDD basis set) and natural orbital analysis.
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页码：604 / 607
页数：3
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