Fluorescence characteristics of dissolved organic matter in several independent water bodies: possible sources and land-use effects

Dissolved organic matter (DOM) plays an important role in aquatic ecosystems. Most previous works have focused on the source, migration, and transformation of DOM in the same water body at several sampling sites, but few studies have focused on the differences in DOM among numerous independent water bodies. This study aimed to investigate the fluorescence properties of DOM and its relationships with water quality indexes, eutrophication levels, and land use in corresponding water catchments in several independent water bodies. Five fluorescent components were identified by the EEM-PARAFAC method in the current study. The UVC humic-like component C1 (λEx/Em = 255/454 nm) and UVA humic-like component C2 (λEx/Em = 260/474 nm) were derived from terrestrial plant decomposition or soil organic matter. The UVA humic-like component C3 (λEx/Em = 300/382 nm) was produced by microbial decomposition. The tryptophan-like component C4 (λEx/Em = 280/330 nm) and the tyrosine-like component C5 (λEx/Em = 225(280)/298 nm) were caused by the discharge of sewage. Farmland contributed more to DOC concentration, humic-like components (C1–C3), and humification index (HIX) than did forest and grassland. The maximum fluorescence intensities of C1, C2, C3, and lna(254) were positively related to the trophic state index (TSI), suggesting that humic-like components and lna(254) could be used as indicators to reflect the eutrophication levels of several independent water bodies.