For the first time, we report here that the development of the novel Ti–Cu–Fe–Co–Ni high entropy alloys (HEAs) via vacuum arc melting technique using non consumable tungsten electrode under high purity Ar atmosphere on a water-cooled copper hearth. Ti–Cu–Fe–Co–Ni multicomponent alloys with varying Ti/Cu (x) molar ratio (x = 1/3, 3/7, 3/5, 9/11, 1, 11/9 and 3/2) have been prepared through the tailoring of microstructure to get understanding of the phase formation and the microstructural evolution of these multicomponent HEAs. X-ray diffraction and scanning electron microscopy coupled with energy dispersive spectroscopic results confirm the presence of (Cu)ss, (Co)ss and (β-Ti)ss dendrites with ultrafine eutectic between cubic (Cu)ss and Laves phase (Ti2Co type). The solidification pathways of novel alloys are critically discussed as follows. For x = 9/11, 1, 11/9 and 3/2; firstly, (β-Ti)ss dendrite is formed from the liquid, followed by the liquid phase separation between the cobalt-rich solid solution (Co)ss and copper-rich solid solution (Cu)ss and finally, the remaining liquid undergoes eutectic reaction between copper solid solution (Cu)ss and the Laves phase (Ti2Co Type), whereas for x = 1/3, 3/7 and 3/5; (β-Ti)ss dendrite is formed first from the liquid and then remaining liquid undergoes the liquid phase separation resulting two different dendrites of (Cu)ss and (Co)ss phases. Detailed thermodynamic calculations have been carried to rationalize the formation of stable solid solution phases of these newly developed multicomponent Ti–Cu–Fe–Co–Ni HEAs.
