Catalytic synthesis of propylene carbonate from propylene oxide and carbon dioxide in the presence of rhodium complexes modified with organophosphorus ligands and chitosan

被引：0
作者：
I. G. Korosteleva
N. A. Markova
N. V. Kolesnichenko
N. N. Ezhova
S. N. Khadzhiev
N. I. Trukhmanova
机构：
[1] Russian Academy of Sciences,Topchiev Institute of Petrochemical Synthesis
来源：
Petroleum Chemistry | 2013年 / 53卷
关键词：
Chitosan; Rhodium; Propylene Glycol; Petroleum Chemistry; Propylene Oxide;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The reaction between CO2 and propylene oxide to produce propylene carbonate in the presence of rhodium complexes modified with organophosphorus ligands and chitosan has been studied. Highly effective catalysts mediating the reaction with almost a 100% yield and 100% selectivity have been prepared using rhodium compounds modified with triphenylphosphine and chitosan.
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页码：412 / 417
页数：5
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