The overall adhesion-spreading process of liposomes on a mercury electrode is controlled by a mixed diffusion and reaction kinetics mechanism

被引：0
作者：
Víctor Agmo Hernández
Michael Hermes
Alexander Milchev
Fritz Scholz
机构：
[1] Uppsala University,Department of Physical and Analytical Chemistry, Division of Physical Chemistry
[2] Universität Greifswald,Institut für Biochemie
[3] Bulgarian Academy of Sciences,Rostislaw Kaischew Institute of Physical Chemistry
来源：
Journal of Solid State Electrochemistry | 2009年 / 13卷
关键词：
Liposomes; Chronoamperometry; Adhesion-spreading; Mercury electrode; DMPC;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Using high-resolution chronoamperometric measurements, with sampling each 1.333 μs, the initial step of the adhesion-spreading of liposomes on a mercury electrode was studied. These measurements allow getting a deeper insight into the first interaction of the liposomes with the mercury electrode, and they show that the overall adhesion-spreading process at different potentials is partially controlled by a fast but weak interaction equilibrium resulting in a mixed diffusion- and reaction-kinetics-controlled mechanism of the overall reaction.
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