X-ray diffraction study of K3[UO2(C2O4)2(NCS)] · 3H2O

被引：0
|
作者：
Yu. N. Mikhailov
I. M. Orlova
R. N. Shchelokov
Yu. E. Gorbunova
Zh. V. Akhmerkina
L. B. Serezhkina
V. N. Serezhkin
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Samara State University,undefined
来源：
Russian Journal of Inorganic Chemistry | 2006年 / 51卷
关键词：
Hydrogen; Potassium; 3H2O; Hydrogen Bond; Inorganic Chemistry;
D O I：
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中图分类号：
学科分类号：
摘要：
The single crystals of K3[UO2(C2O4)2(NCS)] · 3H2O were studied by X-ray diffraction. The compound crystallizes in the monoclinic system, space group P21/n, Z = 4, a = 10.673 Å, b = 12.041 Å, c = 13.856 Å, β = 110.18°, R = 0.0290. The basic structural units of the crystals of I are the island complex groups [UO2(C2O4)2NCS]3− corresponding to the crystal-chemical group AB012M1 (A = UO22+, B01 = C2O42−, M1 = NCS−) of uranyl complexes and connected into a three-dimensional framework through electrostatic interactions and through hydrogen bonds involving potassium ions and water molecules.
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页码：402 / 407
页数：5
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