Homologation of ethylene without metathesis on silica supported ruthenium catalyst

被引：0
|
作者：
Takashi Suzuki
机构：
[1] Gunma Prefectural Industrial Technology Center,
来源：
Reaction Kinetics and Catalysis Letters | 2004年 / 81卷
关键词：
disproportionation; Homologation; metathesis; chain elongation; fischer tropsch synthesis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A 1:1 mixture of 12C2-C2H4 (H2C=CH2) and 13C2-C2H4 (H213C=13CH2) was contacted on Ru/SiO2at 200oC. Propylene (homologation) was observed without 13C1-C2H4 formation (metathesis reaction). This might at least be corroborating evidence for discrimination of active sites in regard with the homologation and the metathesis.
引用
收藏
页码：327 / 331
页数：4
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