Conductivity study of PEO-LiClO4 polymer electrolyte doped with ZnO nanocomposite ceramic filler

被引:0
作者
S. U. Patil
S. S. Yawale
S. P. Yawale
机构
[1] Govt. College of Engineering,Department of Applied Physics
[2] Pre-Indian Administrative Services Training Institute,Department of Physics
[3] Govt. Vidarbha Institute of Science and Humanities,undefined
来源
Bulletin of Materials Science | 2014年 / 37卷
关键词
Composite electrolyte; ceramic filler; poly(ethylene oxide); ZnO; ionic conductivity; impedance spectroscopy;
D O I
暂无
中图分类号
学科分类号
摘要
The preparation and characterization of composite polymer electrolytes comprising PEO and LiClO4 with different concentrations of ZnO nanoparticles are studied. Conductivity measurements were carried out and discussed. In order to ascertain the thermal stability of the polymer electrolyte with maximum conductivity, films were subjected to TG/DTA analysis in the range of 298–823 K. In the present work, FTIR spectroscopy is used to study polymer structure and interactions between PEO and LiClO4, which can make changes in the vibrational modes of the atoms or molecules in the material. FTIR spectra show the complexation of LiClO4 with PEO. The SEM photographs indicated that electrolytes are miscible and homogeneous.
引用
收藏
页码:1403 / 1409
页数:6
相关论文
共 122 条
  • [1] Ahn J H(2003)undefined J. Power Sources 422 119-undefined
  • [2] Wang G X(2003)undefined Electrochem. Acta 2239 48-undefined
  • [3] Liu H K(1999)undefined Solid State Ionics 73 118-undefined
  • [4] Dou S X(2003)undefined J. Power Sources 288 115-undefined
  • [5] Blaoise A C(2001)undefined J. Power Sources 644 97-undefined
  • [6] Donoso J P(1995)undefined Nature 557 373-undefined
  • [7] Magon C J(1999)undefined J. Phys. Chem. B103 10632-undefined
  • [8] Rosario A V(2001)undefined Electrochim. Acta 2457 46-undefined
  • [9] Pereira E C(2004)undefined Solid State Ionics 73 170-undefined
  • [10] Capiglia C(2002)undefined Solid State Ionics 29 149-undefined