Synthesis of new charge-compensated cobalt bis(1,2-dicarbollide) derivatives

被引：0

作者：

I. D. Kosenko

I. A. Lobanova

Z. A. Starikova

V. I. Bregadze

机构：

[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds

来源：

Russian Chemical Bulletin | 2013年 / 62卷

关键词：

cobalt bis(1,2-dicarbollide); charge-compensated derivatives; 8,8′-μ-iodo-3-; -3-cobalta-bis(1,2-dicarba-; -dodecaborane); reactivity; X-ray diffraction studies;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

New hetero-substituted charge-compensated cobalt bis(1,2-dicarbollide) derivatives were synthesized by the reaction of 8,8′-μ-iodo-3-commo-3-cobalta-bis(1,2-dicarba-closo-dodecaborane) [8,8′-μ-I-3,3′-Co(1,2-C2B9H10)2] with 1,4-thioxane, pyridine N-oxide, and tetrahydropyran. X-ray diffraction studies showed that the 8′-iodo-8-(pyridiniumoxy)eucosahydro-1,1′,2,2′-tetracarba-3-commo-cobalta-closo-tricosaborate molecule has the gauche-conformation (the substituents are turned with respect to each other by 69.2°). The positive charge is predominantly localized on the N(Py) atom.

引用

收藏

页码：1914 / 1918

页数：4

相关论文

共 50 条

[31] Synthesis, radiosynthesis and biological evaluation of 1,4-dihydroquinoline derivatives as new carriers for specific brain delivery [J].

Foucout, Lenaig ;

Gourand, Fabienne ;

Dhilly, Martine ;

Bohn, Pierre ;

Dupas, Georges ;

Costentin, Jean ;

Abbas, Ahmed ;

Marsais, Francis ;

Barre, Louisa ;

Levacher, Vincent .

ORGANIC & BIOMOLECULAR CHEMISTRY, 2009, 7 (18) :3666-3673

[32] Efficient synthesis of 1,2-bis(alkoxycarbonyl)-pyrazol-3-ones from 2,3-allenoic acids, azodicarboxylates and PPh3 [J].

Lu, Ruizhi ;

Cheng, Xin ;

Zheng, Xingliang ;

Ma, Shengming .

CHEMICAL COMMUNICATIONS, 2014, 50 (13) :1537-1539

[33] Synthesis of C-Mercuro Derivatives of ortho-Carborane. Crystal Structure of Bis(2-phenyl-ortho-carboran-1-yl)mercury [J].

Anufriev, S. A. ;

Timofeev, S. V. ;

Nasyrova, D. I. ;

Sivaev, I. B. ;

Bregadze, V. I. .

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2024, 69 (05) :625-629

[34] One-Pot Three-Component Synthesis of 3-nitro-2-arylimidazo[1,2-a]pyridine Derivatives Using Air as an Oxidant [J].

Yan, Hao ;

Yan, Rulong ;

Yang, Sizhuo ;

Gao, Xiai ;

Wang, Yuling ;

Huang, Guosheng ;

Liang, Yongmin .

CHEMISTRY-AN ASIAN JOURNAL, 2012, 7 (09) :2028-2031

[35] New Polymorph of 1,3-Bis(2,6-di-isopropylphenyl)-4,5-Dichloroimidazole-2-Ylidene and a Cobalt Complex with this Compound [J].

Petrov, P. A. ;

Nikolaevskii, S. A. ;

Filippova, E. A. ;

Kompankov, N. B. ;

Sukhikh, T. S. ;

Kiskin, M. A. ;

Sokolov, M. N. ;

Eremenko, I. L. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2024, 65 (01) :117-124

[36] Structural diversity in manganese, iron and cobalt complexes of the ditopic 1,2-bis(2,2′-bipyridyl-6-yl)ethyne ligand and observation of epoxidation and catalase activity of manganese compounds [J].

Madhu, Vedichi ;

Ekambaram, Balaraman ;

Shimon, Linda J. W. ;

Diskin, Yael ;

Leitus, Gregory ;

Neumann, Ronny .

DALTON TRANSACTIONS, 2010, 39 (31) :7266-7275

[37] Synthesis and Characterization of 3-Chloropropyl-substituted o-Carboranes: Crystal Structures of 1,2-(1,3-Propanediyl)-o-carborane, 1-(3-Chloropropyl)-o-carborane and 1,2-Bis(3-chloropropyl)-o-carborane [J].

Bian, Deqian ;

Nie, Yong ;

Miao, Jinling ;

Zhang, Zhenwei ;

Lu, Ping .

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (07) :804-810

[38] SYNTHESIS AND STRUCTURE OF NEW Er(III) COMPLEXES WITH N,N′-1,3-BIS(2,6-DIISOPROPYLPHENYL)TRIAZENIDE [J].

Kolybalov, D. S. ;

Sukhikh, T. S. ;

Bashirov, D. A. ;

Konchenko, S. N. .

JOURNAL OF STRUCTURAL CHEMISTRY, 2021, 62 (02) :277-284

[39] New 1,2,3-triazole based bis- and trisphosphine ligands: synthesis, transition metal chemistry and catalytic studies [J].

Radhakrishna, Latchupatula ;

Kunchur, Harish S. ;

Namdeo, Pavan K. ;

Butcher, Ray J. ;

Balakrishna, Maravanji S. .

DALTON TRANSACTIONS, 2020, 49 (11) :3434-3449

[40] Synthesis of Pyrazolo[1,5-a][1,3,5]triazine, Pyrazolo[1,5-a]pyrimidine, and Imidazo[1,2-b]pyrazole Derivatives Based on Imidazo[2,1-b]thiazole Moiety [J].

Dawood, Kamal M. ;

Sayed, Samia M. ;

Raslan, Mohamed A. .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 2017, 54 (04) :2405-2416

← 1 2 3 4 5 →