Kinetics and mechanism of reaction between polyfluorinated alcohols and thionyl chloride

被引：0

作者：

A. I. Rakhimov

Yu. V. Popov

V. M. Volchkov

O. V. Vostrikova

E. A. Zauer

机构：

[1] Volgograd State Technical University,

来源：

Russian Journal of Organic Chemistry | 2004年 / 40卷

关键词：

Alcohol; Spectroscopy; Chloride; Organic Chemistry; Heat Flux;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Complexing of polyfluorinated alcohols with triethylamine was studied by means of microcalorimetry, IR and NMR spectroscopy. The reaction kinetics of these polar complexes with thionyl chloride was investigated using calorimetry of heat fluxes applying mathematical simulation procedure. The second order of nucleophilic substitution reaction of chlorine by polyfluoroalkoxy group was established.

引用

页码：1579 / 1582

页数：3