Mechanism of lactic acid formation catalyzed by tetraamine rhodium(III) complexes

被引：0
作者：
Jette Eriksen
Ole Mønsted
Lene Mønsted
机构：
[1] University of Copenhagen,Department of Chemistry
[2] Royal Veterinary and Agricultural University,Department of Chemistry
来源：
Transition Metal Chemistry | 1998年 / 23卷
关键词：
Lactate; Hydrogen Atom; Lactic Acid; Hydride; Diamine;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The transformation of methylglyoxal and of 1,3–dihydroxyacetone and glyceraldehyde into lactic acid can be catalyzed by cis- tetraaminediaquarhodium(III) complexes of ethane-1,2–diamine and of the macrocyclic racemic 5,5,7,12,12,14–hexamethyl-1,4,8,11– tetraazacyclotetradecane ligand. The detailed stoichiometry of this process has been investigated by isotopic labelling studies and 1H and 13C-n.m.r. spectroscopy.
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页码：783 / 787
页数：4
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