Molecular and Crystal Structure of (1S,2R)-1-{2-[(1S)-1-(Dimethylamino)Ethyl]Phenyl}-1,2-Diphenylethane-1,2-Diol

被引：0
|
作者：
V. M. Demyanovich
I. N. Shishkina
K. A. Potekhin
A. V. Maleev
A. A. Gevorgyan
机构：
[1] Moscow State University,
[2] Vladimir State University,undefined
来源：
Journal of Structural Chemistry | 2019年 / 60卷
关键词：
aminoalcohols; aminoketoalcohols; reduction; stereoselectivity; configuration; atom-atom potentials; molecular agglomerates in crystals;
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学科分类号：
摘要：
The (R)-configuration of the carbinol center formed as a result of diastereospecific reduction of (2S)-2-{2-(1S)-1-(dimethylamino)ethyl]phenyl}-2-hydroxy-1,2-diphenylethanone is established by the XRD method. The analysis of shortened nonvalent intramolecular contacts testifies that the molecule is quite rigid, despite the presence of a large number of single valence bonds. Layered nature of molecular packaging is revealed.
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页码：654 / 661
页数：7
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