Effect of Polyethylene Glycol on the Structure and Catalytic Properties of 1% Pd/ZnO Nanocomposites in the Selective Hydrogenation of Acetylenic Alcohols

被引:0
作者
A. K. Zharmagambetova
E. T. Talgatov
A. S. Auyezkhanova
Kh. Rafikova
A. T. Zamanbekova
N. Zh. Tumabayev
机构
[1] D. V. Sokolskiy Institute of Fuel,
[2] Catalysis and Electrochemistry,undefined
[3] Satbayev University,undefined
[4] Kazakh Academy of Architecture and Civil Engineering,undefined
来源
Theoretical and Experimental Chemistry | 2018年 / 54卷
关键词
selective hydrogenation; 3,7,15-trimethyldodecyn-1-ol-3; 3,7,11,15-tetramethylhexadecyn-1-ol-3; palladium catalyst; polyethylene glycol; selectivity; stability;
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学科分类号
摘要
It is shown that modification of zinc oxide with polyethylene glycol leads to an increase in the catalytic activity of 1% Pd/ZnO nanocomposites in the low-temperature selective hydrogenation of acetylenic alcohols. This effect is due to the formation of palladium nanoparticles 2-4 nm in size in the polymer layer attached to the surface of the zinc oxide.
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页码:265 / 273
页数:8
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