Addition of carbon dioxide to epoxides catalyzed by the mixtures of α-amino acids and iodine

被引：0

作者：

S. E. Lyubimov

P. V. Cherkasova

R. R. Aysin

B. Chowdhury

机构：

[1] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds

[2] Indian Institute of Technology (Indian School of Mines),Department of Chemistry

来源：

Russian Chemical Bulletin | 2022年 / 71卷

关键词：

carbon dioxide; amino acids; iodine; epoxides; CO; fixation; carbonates;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

We found a group of available and efficient catalysts for the addition reaction of CO2 to epoxides, which was formed by simple mixing of molecular iodine with α-amino acids. Analysis of the spectral characteristics of the proline—iodine mixture, which showed the highest activity, suggests its existence as an equilibrium structure such as [proline—I]+I−.

引用

页码：408 / 411

页数：3

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