Molecular and crystal structure of the echinochrome complex with dioxane

被引:0
作者
A. V. Gerasimenko
S. A. Fedoreyev
N. P. Mischenko
机构
[1] Russian Academy of Sciences,Institute of Chemistry, Far East Division
[2] Russian Academy of Sciences,Pacific Institute of Bioorganic Chemistry, Far East Division
来源
Crystallography Reports | 2006年 / 51卷
关键词
Crystal Structure; Dioxane; Thin Plate; Molecular Complex; Crystal Data;
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摘要
The molecular and crystal structures of a complex of echinochrome (2,3,5,6,8-pentahydroxy-7-ethyl-1,4-naphthoquinone) with dioxane are determined. The molecular complex 2(C12H10O7) · C4H8O2 crystallizes in the form of dark red transparent thin plates. The crystal data of the compound are as follows: a = 4.563(1) Å, b = 6.382(1) Å, c = 22.812(4) Å, α = 91.955(5)°, β = 90.408(5)°, γ = 104.801(4)°, space group \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document} $$P\overline 1 $$ \end{document}, and Z = 2. The crystal structure is solved by direct methods and refined to R1 = 0.0656 and wR2 = 0.1196.
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页码:42 / 46
页数:4
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