Phase equilibria in the BaO-Bi2O3-B2O3 system

被引：0
|
作者：
A. V. Egorysheva
V. M. Skorikov
V. D. Volodin
O. E. Myslitskii
Yu. F. Kargin
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Russian Journal of Inorganic Chemistry | 2006年 / 51卷
关键词：
Isothermal Section; Ternary Compound; High Purity Grade; Barium Borate; Bismuth Borate;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Phase equilibria in the BaO-Bi2O3-B2O3 system have been investigated by X-ray powder diffraction analysis and DTA. Quasi-binary sections have been determined, and an isothermal section of the system in the subsolidus region has been constructed. The BaO-Bi2O3-B2O3 ternary system has been divided into 22 triangles of coexisting phases. It has been found that four bismuth barium borates exist, namely, Ba3BiB3O9, BaBi2B4O10, BaBiB11O19, and BaBiBO4. Ba3BiB3O9 undergoes a phase transition at 850°C and exists up to 885°C, where it decomposes in the solid state. BaBiB11O19 and BaBi2B4O10 melt congruently at 807 and 730°C, respectively. BaBiBO4 melts incongruently at 780°C. X-ray powder diffraction data for the low-temperature polymorph of Ba3BiB3O9 are presented.
引用
收藏
页码：1956 / 1960
页数：4
相关论文
共 50 条
  • [1] Phase equilibria in the BaO-Bi2O3-B2O3 system
    Egorysheva, A. V.
    Skorikov, V. M.
    Volodin, V. D.
    Myslitskii, O. E.
    Kargin, Yu. F.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2006, 51 (12) : 1956 - 1960
  • [2] FLUX SYSTEM BAO-BI2O3-B2O3
    ELWELL, D
    MORRIS, AW
    NEATE, BW
    JOURNAL OF CRYSTAL GROWTH, 1972, 16 (01) : 67 - &
  • [3] A study of the phase and glass forming diagrams of the BaO-Bi2O3-B2O3 system
    Hovhannisyan, Martun R.
    Hovhannisyan, Rafael M.
    Grigoryan, Bela V.
    Alexanyan, Hovakim A.
    Knyazyan, Nikolay B.
    GLASS TECHNOLOGY-EUROPEAN JOURNAL OF GLASS SCIENCE AND TECHNOLOGY PART A, 2009, 50 (06): : 323 - 328
  • [4] Phase, glass formation and the properties of BaO-Bi2O3-B2O3 glasses
    Bobkova, N. M.
    Trusova, E. E.
    Zakharevich, G. B.
    GLASS AND CERAMICS, 2013, 69 (11-12) : 366 - 369
  • [5] Study of stoichiometrich glass ceramics formation in the BaO-Bi2O3-B2O3 system
    Hovhannisyan, Martun Rafael
    Hovhannisyan, Rafael M.
    Alexanyan, Hovakim A.
    Grigoryan, Bela V.
    Knyazyan, Nikolay B.
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : C513 - C513
  • [6] Luminescence of europium-doped BaO-Bi2O3-B2O3 glasses
    A. V. Egorysheva
    V. D. Volodin
    A. A. Chistyakov
    Yu. A. Kuzishchin
    V. M. Skorikov
    T. D. Dudkina
    Inorganic Materials, 2010, 46 : 1384 - 1390
  • [7] Luminescence of europium-doped BaO-Bi2O3-B2O3 glasses
    Egorysheva, A. V.
    Volodin, V. D.
    Chistyakov, A. A.
    Kuzishchin, Yu. A.
    Skorikov, V. M.
    Dudkina, T. D.
    INORGANIC MATERIALS, 2010, 46 (12) : 1384 - 1390
  • [8] Effect of Eu2O3 doping on the crystallization behavior of BaO-Bi2O3-B2O3 glasses
    A. V. Egorysheva
    V. D. Volodin
    I. V. Berezovskaya
    E. V. Zubar’
    V. M. Skorikov
    T. Milenov
    P. Rafailov
    Inorganic Materials, 2012, 48 : 948 - 952
  • [9] Sintering behavior and dielectric properties of BaTiO3 added with BaO-Bi2O3-B2O3 glass phase
    Li, Tingting
    Segawa, Hiroyo
    Ohashi, Naoki
    CERAMICS INTERNATIONAL, 2018, 44 (11) : 13004 - 13010
  • [10] Effect of Eu2O3 doping on the crystallization behavior of BaO-Bi2O3-B2O3 glasses
    Egorysheva, A. V.
    Volodin, V. D.
    Berezovskaya, I. V.
    Zubar', E. V.
    Skorikov, V. M.
    Milenov, T.
    Rafailov, P.
    INORGANIC MATERIALS, 2012, 48 (09) : 948 - 952
12345