Electrochemical oxidation of 2H-imidazole N-oxides

被引：0
|
作者：
I. G. Irtegova
V. F. Starichenko
I. A. Kirilyuk
I. A. Grigor"ev
机构：
[1] N. N. Vorozhtsov Institute of Organic Chemistry,Siberian Branch of the Russian Academy of Sciences
来源：
Russian Chemical Bulletin | 2002年 / 51卷
关键词：
2; -imidazole ; -oxides; electrooxidation; radical cations;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Electrochemical oxidation of 2H-imidazole N-oxides was studied using cyclic voltammetry and ESR spectroscopy. The formation of the 2,2-dimethyl-4,5-diphenyl-2H-imidazole 1,3-dioxide radical cation was noticed for the first time. The possibility of reaction between the 2H-imidazole N,N-dioxide radical cation and methanol including the detachment of a hydrogen atom from the MeOH methyl group was demonstrated.
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页码：2065 / 2069
页数：4
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