Electrochemical oxidation of 2H-imidazole N-oxides

被引：0

作者：

I. G. Irtegova

V. F. Starichenko

I. A. Kirilyuk

I. A. Grigor"ev

机构：

[1] N. N. Vorozhtsov Institute of Organic Chemistry,Siberian Branch of the Russian Academy of Sciences

来源：

Russian Chemical Bulletin | 2002年 / 51卷

关键词：

2; -imidazole ; -oxides; electrooxidation; radical cations;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Electrochemical oxidation of 2H-imidazole N-oxides was studied using cyclic voltammetry and ESR spectroscopy. The formation of the 2,2-dimethyl-4,5-diphenyl-2H-imidazole 1,3-dioxide radical cation was noticed for the first time. The possibility of reaction between the 2H-imidazole N,N-dioxide radical cation and methanol including the detachment of a hydrogen atom from the MeOH methyl group was demonstrated.

引用

页码：2065 / 2069

页数：4

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