The influence of laser focusing on the intensity of spectral lines in femtosecond laser-induced breakdown spectroscopy of liquids

被引:0
作者
S. S. Golik
A. A. Ilyin
A. V. Kolesnikov
M. Yu. Babiy
Yu. N. Kul’chin
O. A. Bukin
机构
[1] Russian Academy of Sciences,Institute of Automation and Control Processes, Far East Branch
[2] Far Eastern Federal University,undefined
来源
Technical Physics Letters | 2013年 / 39卷
关键词
Technical Physic Letter; Femtosecond Laser Pulse; Plasma Channel; Laser Induce Breakdown Spectroscopy; Optical Breakdown;
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摘要
The influence of the diameter of the beam of a femtosecond Ti:Sapphire laser (800 nm, 40 fs, 0.8 mJ) on the intensity of spectral lines upon optical breakdown on the surface of CaCl2 aqueous solution has been determined experimentally. It is shown that an increase in the laser-beam diameter from 7 to 14 mm on a focusing lens for identical pulse energy increases the intensities of the CaII (393.3 nm) and Hα (656 nm) lines by factors of 3 and 20, respectively. This effect can be used to increase the intensities of emission lines of chemical elements in femtosecond laser-induced breakdown spectroscopy of liquids and, accordingly, improve the sensitivity of this method.
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页码:702 / 704
页数:2
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