Synthesis, crystal structure, and magnetic characteristics of chiral cyanide-bridged Fe–Cu complex

被引：0
作者：
C. Xue
H. Yuan
H. Zhang
D. Zhang
机构：
[1] Shandong University of Technology,College of Chemical Engineering
[2] Jiangxi Institute of Materia Medica,undefined
来源：
Russian Journal of General Chemistry | 2016年 / 86卷
关键词：
chiral; cyanide-bridged; crystal structure; magnetic property;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Based on the building blocks, trans-dicyanide Fe(III) precursor and chiral amine Cu(II) compound, the chiral cyanide-bridged heterometallic Fe(III)–Cu(II) complex with the formula {[Cu(R/R-Chxn)2Fe(bpmb)·(CN)2][Fe(bpmb)(CN)2]}·CH3OH·H2O (1) [bpmb2– = 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate, R,R-Chxn = R,R-1,2-diaminocyclohexane] has been synthesized and characterized by elemental analysis, IR spectra and X-ray analysis. The latter revealed that the complex contained the cyanide-bridged cationic binuclear entity and free anionic cyanide building block. The complex demonstrated weak ferromagnetic coupling between neighboring Fe(III) and Cu(II) ions via the bridging cyanide group.
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页码：953 / 957
页数：4
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