Synthesis and structure of the polymeric cluster compound [Mn(H2O)4]3[W4S4(CN)12]·nH2O containing very large cavities

被引：0
作者：
V. P. Fedin
I. V. Kalinina
A. V. Virovets
D. Fenske
机构：
[1] Siberian Branch of the Russian Academy of Sciences,Institute of Inorganic Chemistry
[2] Universität Karlsruhe,Institüt für Anorganishe Chemie
来源：
Russian Chemical Bulletin | 2001年 / 50卷
关键词：
tungsten; cluster complexes; sulfide complexes; synthesis; X-ray diffraction analysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The compound [Mn(H2O)4]3[W4S4(CN)12]·nH2O (1) was prepared by the reaction of an aqueous solution of MnSO4 with a glycerol solution of KCs5[W4S4(CN)12]·4H2O. Complex 1 was characterized by X-ray diffraction analysis and IR spectroscopy. According to the X-ray diffraction data, the three-dimensional polymeric framework of 1 comprises only 24.2% of the unit-cell volume. The volume of the cavities per formula unit is 1664 Å3. The cavities are occupied by highly disordered water molecules.
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页码：1525 / 1528
页数：3
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