Electronic Structure and Nature of the Chemical Bonds of a Transition Metal with a Non-Innocent Ligand in Coordination Complex Na3[Mo(NO)(NH2O){N(CH2PO3)3H}] · 8H2O

被引：0

作者：

Chausov F.F. ^{[1
,2
]}

Somov N.V. ^{[3
]}

Lomova N.V. ^{[1
]}

Shabanova I.N. ^{[1
]}

Zakirova R.M. ^{[2
]}

Petrov V.G. ^{[4
]}

Shumilova M.A. ^{[4
]}

机构：

[1] Physical and Technical Institute, Ural Branch, Russian Academy of Sciences, Izhevsk

[2] Udmurt State University, Izhevsk

[3] Lobachevsky National Research University, Nizhny Novgorod

[4] Institute of Mechanics, Ural Branch, Russian Academy of Sciences, Izhevsk

来源：

Bulletin of the Russian Academy of Sciences: Physics | 2018年 / 82卷 / 7期

关键词：

D O I：

10.3103/S1062873818070146

中图分类号：

学科分类号：

摘要：

A heteroleptic complex of molybdenum with nitrilotris(methylenephosphonic acid), hydroxylamine, and nitrogen(II) oxide is investigated via single-crystal X-ray diffraction (SXRD) and X-ray photoelectron spectroscopy (XPS). It is established that the actual charge on the Mo atom is around +1e, despite the formal oxidation state of molybdenum being +3. The electron density is mostly localized in the Mo–NO bond, and the distribution of the electron density is indicative of the formation of a π-bond. © 2018, Allerton Press, Inc.

引用

页码：892 / 894

页数：2

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