Kinetics of acid-base interaction of octaphenyl-substituted tetraazaporphyrins with nitrogen-containing bases in a system benzene-dimethylsulfoxide

被引：0

作者：

O. A. Petrov

N. V. Chizhova

G. V. Osipova

机构：

[1] Ivanovo State Chemical Technological University,Institute of the Chemistry of Solutions

[2] Russian Academy of Sciences,undefined

来源：

Russian Journal of General Chemistry | 2009年 / 79卷

关键词：

General Chemistry; High Occupied Molecular Orbital; Lower Unoccupied Molecular Orbital; Macrocycle; Base Interaction;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Effect of dimethylsulfoxide additives on the kinetics of acid-base interaction of octaphenyl-substituted tetraazaporphyrins with nitrogen-containing bases in benzene is studied. A strong effect of the solvent on the process rate and activation parameters is revealed. The relation of the molecular structure of the interacting molecules to their reactivity is demonstrated.

引用

共 48 条

[1] Kinetics of acid-base interaction of octaphenyl-substituted tetraazaporphyrins with nitrogen-containing bases in a system benzene-dimethylsulfoxide
Petrov, O. A.
Chizhova, N. V.
Osipova, G. V.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2009, 79 (04) : 839 - 844
[2] Kinetics and Mechanism of Magnesium Acetate Complexation with Octaphenyl-Substituted Tetraazaporphyrins in the System Dimethyl Sulfoxide-Benzene
O. A. Petrov
N. V. Chizhova
Russian Journal of General Chemistry, 2002, 72 : 295 - 299
[3] Kinetics of Proton Transfer from Octa(m-trifluoromethylphenyl)porphyrazine to Nitrogen-Containing Bases in the Benzene-Dimethylsulfoxide System
Petrov, O. A.
Osipova, G. V.
Aganicheva, K. A.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2020, 94 (01) : 48 - 53
[4] Kinetics and mechanism of magnesium acetate complexation with octaphenyl-substituted tetraazaporphyrins in the system dimethyl sulfoxide-benzene
Petrov, OA
Chizhova, NV
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2002, 72 (02) : 295 - 299
[5] Characteristics of intermolecular transfer of sterically screened protons of octaphenyl-substituted tetraazaporphyrins in the N-base-benzene system
Petrov, OA
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY, 2002, 76 (09): : 1423 - 1428
[6] The effect of steric hindrances on the kinetics of acid-base interaction of octa(p-nitrophenyl)tetraazaporphin with nitrogen-containing bases in benzene
Petrov, OA
Chizhova, NV
ZHURNAL FIZICHESKOI KHIMII, 1999, 73 (03): : 450 - 455
[7] Reactivity of tetraazaporphyrins in the acid-base interactions with nitrogen bases
Petrov, O. A.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2013, 83 (04) : 762 - 770
[8] Reactivity of tetraazaporphyrins in the acid-base interactions with nitrogen bases
O. A. Petrov
Russian Journal of General Chemistry, 2013, 83 : 762 - 770
[9] Kinetics of Proton Transfer from Octa(m-trifluoromethylphenyl)porphyrazine to Nitrogen-Containing Bases in the Benzene–Dimethylsulfoxide System
O. A. Petrov
G. V. Osipova
K. A. Aganicheva
Russian Journal of Physical Chemistry A, 2020, 94 : 48 - 53
[10] Kinetics of the Acid-Base Interaction between Tetra(4-tert-butyl)phthalocyanine and Nitrogen-Containing Bases in Dimethyl Sulfoxide
O. A. Petrov
G. V. Osipova
A. S. Semeikin
B. D. Berezin
Russian Journal of Coordination Chemistry, 2005, 31 : 894 - 898

← 1 2 3 4 5 →