Zn complex with N-(4′-Benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine: Synthesis, crystal structure, and vibration spectrum

被引：0
|
作者：
L. Kh. Minacheva
I. S. Ivanova
A. V. Dorokhov
A. S. Burlov
A. D. Garnovskii
V. S. Segienko
A. Yu. Tsivadze
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
[2] Rostov State University,Institute of Physical and Organic Chemistry
[3] Russian Academy of Sciences,Institute of Physical Chemistry
来源：
Russian Journal of Coordination Chemistry | 2006年 / 32卷
关键词：
Spectroscopy; Reflection; Physical Chemistry; Crystal Structure; Inorganic Chemistry;
D O I：
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摘要：
The ZnL2 complex (I) (HL = N-(4′-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine) is synthesized and studied by IR spectroscopy and X-ray diffraction analysis. The crystals are monoclinic: a = 23.139(2) Å, b = 19.931(2) Å, c = 14.604(2) Å, β = 121.20(1)°, Z = 4, space group C2/c, R = 0.751 for 766 reflections with I > 2σ(I). The Zn atom in a molecule of the complex lies on a twofold axis and is coordinated at the vertices of a distorted tetrahedron by four N atoms of two HL ligands (average Zn-N distance 2.024 Å).
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页码：166 / 172
页数：6
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