Electronic structure of europium(iii) acrylate and methacrylate: an X-ray photoelectron spectroscopy and quantum chemical study

被引:0
作者
V. V. Korochentsev
E. V. Mikhailenko
A. V. Shurygin
V. I. Vovna
I. S. Os’mushko
A. G. Mirochnik
N. V. Petrochenkova
机构
[1] Far Eastern Federal University,Institute of Chemistry
[2] Far Eastern Branch of the Russian Academy of Sciences,undefined
来源
Russian Chemical Bulletin | 2017年 / 66卷
关键词
X-ray electron spectroscopy; density functional theory; carboxylates; electronic structure; rare-earth elements; Eu;
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学科分类号
摘要
The electronic structure and specific features of the nature of chemical bonding in europium acrylate and europium methacrylate were investigated by X-ray photoelectron spectroscopy (XPS) and quantum chemistry methods. The effect of the replacement of acrylic acid by methacrylic acid was also studied. The assignment of bands in the valence region XPS spectra is proposed.
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页码:2081 / 2089
页数:8
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