General relations in heterogeneous alkylation of sodium carbonate in dimethyl sulfoxide

被引：0

作者：

E. K. Slipchenko

A. F. Choban

A. S. Lyavinets

K. A. Chervinskii

机构：

[1] Yurii Fed’kovich National University,

来源：

Russian Journal of General Chemistry | 2006年 / 76卷

关键词：

Sodium; Dimethyl; General Relation; Sulfoxide; Dimethyl Sulfoxide;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The kinetics of alkylation of sodium carbonate with 1-bromobutane in dimethyl sulfoxide were studied. The reaction was revealed to tend to autoinhibition. The mechanism of autoinhibition was established, ways of avoiding it were proposed, and the role of solvent in this process was described. Carbonate ion was found to react as ion pair with specifically solvated sodium cation.

引用

页码：55 / 58

页数：3

共 9 条

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[5]

Parker A.Dzh.(undefined)undefined undefined undefined undefined-undefined

[6]

Trofimov B.A.(undefined)undefined undefined undefined undefined-undefined

[7]

Lyavinets A.S.(undefined)undefined undefined undefined undefined-undefined

[8]

Choban A.F.(undefined)undefined undefined undefined undefined-undefined

[9]

Chervinskii K.A.(undefined)undefined undefined undefined undefined-undefined

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