Copolymers of 2-(3-mesityl-3-methylcyclobutyl)-2-ketoethyl Methacrylate with Acrylonitrile and Styrene: Synthesis, Characterization, and Monomer Reactivity Ratios

被引：0
作者：
Ibrahim Erol
Mısır Ahmedzade
机构：
[1] University of Afyon Kocatepe,Department of Chemistry, Faculty of Science and Arts
[2] University of Fırat,Department of Chemistry, Faculty of Science and Arts
来源：
Journal of Polymer Research | 2005年 / 12卷
关键词：
copolymers; cyclobutane; ketoethyl methacrylate; monomer reactivity ratios;
D O I：
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学科分类号：
摘要：
The copolymerization of 2-(3-mesityl-3-methylcyclobutyl)-2-ketoethyl methacrylate monomer with acrylonitrile and styrene were carried out in 1,4-dioxane solution at 60 ○C using AIBN as an initiator. The copolymers were characterized by Fourier transform infrared, 1H-NMR, and 13C-NMR spectroscopic techniques. Thermal properties of the polymers were also studied by thermogravimetric analysis and differential scanning calorimetry. The copolymer compositions were determined by elemental analysis and 1H-NMR technique. The monomer reactivity ratios were calculated by the application of conventional linearization methods as a result of Fineman–Ross and Kelen–Tüdös to less than 1 for both monomers.
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页码：247 / 255
页数：8
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