Spatial structure of molecular complexes of zinc(II)tetraphenylporphyrin with pyridine and aniline derivatives

被引：0
|
作者：
P. S. Sobolev
V. P. Andreev
T. A. Ekimova
机构：
[1] Petrozavodsk State University,
来源：
Russian Journal of General Chemistry | 2014年 / 84卷
关键词：
pyridine; aniline; tetraphenylporphyrin; X-ray diffraction; rehybriization;
D O I：
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中图分类号：
学科分类号：
摘要：
Structure of molecular complexes of zinc(II)tetraphenylporphyrin with 4-dimethylaminopyridine and 4-methoxyaniline has been studied by X-ray diffraction analysis. 4-Dimethylaminopyridine is coordinated almost perpendicular to the porphyrin cycle plane, whereas 4-methoxyaniline is coordinated at lower dihedral angle. The hybridization of aniline nitrogen atom in the crystal depends on donor-acceptor properties and the volume of the substituents in the aromatic ring.
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页码：1399 / 1403
页数：4
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