Supported CuO/Ce1−xZrxO2 catalysts for the preferential oxidation of CO in H2-rich gases

被引:0
作者
T. Caputo
R. Pirone
G. Russo
机构
[1] Universitá degli studi di Napoli “Federico II”,Dipartimento di ingegneria chimica
[2] Istituto di Ricerche sulla Combustione,undefined
[3] CNR,undefined
来源
Kinetics and Catalysis | 2006年 / 47卷
关键词
Ceria; Preferential Oxidation; Pure Ceria; Fuel Processor; Prox Reaction;
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学科分类号
摘要
The catalytic properties of CuO supported on ceria or ceria-zirconia mixed oxides have been investigated in the preferential oxidation of CO in H2-rich gases. CuO/CeO2 shows very high activity towards the oxidation of CO with a light-off temperature of about 70°C. This catalyst is very selective for the oxidation of CO rather than of H2 in the low temperature region (70–120°C), while at higher temperatures, the oxidation of hydrogen begins, causing of a maximum of CO conversion to arise with increasing temperature.
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页码:756 / 764
页数:8
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共 76 条
[1]  
Trimm D.L.(2000)undefined Catal. Rev. 43 31-undefined
[2]  
Onsan Z.I.(1993)undefined J. Catal. 142 254-undefined
[3]  
Oh S.H.(1997)undefined J. Catal. 171 93-undefined
[4]  
Sinkevitch M.R.(1997)undefined Appl. Catal., A 159 159-undefined
[5]  
Kahlich M.J.(1993)undefined J. Catal. 144 175-undefined
[6]  
Gasteiger H.A.(1999)undefined J. Power Sources 84 175-undefined
[7]  
Behm R.(1997)undefined J. Catal. 168 125-undefined
[8]  
Iragashi H.(1999)undefined J. Catal. 182 430-undefined
[9]  
Uchida H.(2001)undefined Catal. Lett. 73 33-undefined
[10]  
Suzuki M.(2002)undefined Catal. Today 75 157-undefined