Synthesis and characterization of a new fluorene ligand and its complexes with cobalt(II), copper(II), and ruthenium(II)

被引：0

作者：

İbrahim Erden

Ali Erdoğmuş

Nebahat Demirhan

Ulvi Avcıata

机构：

[1] Yildiz Technical University,Faculty of Arts and Sciences Chemistry Department

来源：

Transition Metal Chemistry | 2008年 / 33卷

关键词：

Schiff Base; Crown Ether; Free Ligand; Crown Ether Moiety; Emission Band Maximum;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A new fluorene ligand, benzo[15-crown-5]-5H-pyrido[3′,2′:4,5]cylopenta[1,2-b]pyridin-5-ylidenehydrazone (bph), has been synthesized from the reaction of 4,5-diazafluoren-9-one with 4′-formylbenzo-15-crown-5. The Co(II), Cu(II), and Ru(II) complexes of the ligand were prepared and characterized. The metal-to-ligand ratio of the Co(II) and Cu(II) complexes was found to be 2:1 and that of the Ru(II) complex was found to be 1:1. The ligand and complexes have been characterized by FTIR, UV–visible, 1H NMR and fluorescence spectra, as well as elemental analyses and mass spectra.

引用

页码：439 / 442

页数：3

共 50 条

[21] Synthesis, Characterization, Antibacterial and Antifungal Activities Studies of Copper(II), Cobalt(II) and Zinc(II) Complexes of the Schiff Base Ligand Derived from 4,4-Diaminodiphenylether
Sahal, Hakan
Canpolat, Erdal
Kaya, Mehmet
Gur, Seher
JOURNAL OF THE CHEMICAL SOCIETY OF PAKISTAN, 2014, 36 (01): : 106 - 112
[22] Synthesis and Characterization of New D-π-A Type Fluorene Ligands and Their Ru(II) Complexes
Erden, Ibrahim
Kilicarslan, Fatma Aytan
Erdogmus, Ali
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY, 2015, 45 (11) : 1733 - 1738
[23] Synthesis, Spectroscopic and Biological Characterization of the Mn(II), Co(II), Ni(II), Cu(II) and Zn(II) Complexes with a New Macrocylic Tridentate [ONO] Ligand
Bootwala, Sakina
Aruna, K.
ASIAN JOURNAL OF CHEMISTRY, 2012, 24 (05) : 2125 - 2131
[24] Cobalt(II), copper(II), nickel(II), and Zinc(II) complexes of naphthaldehyde thiazolyl hydrazones
Yilmaz, I
Çukurovali, A
POLISH JOURNAL OF CHEMISTRY, 2004, 78 (05) : 663 - 672
[25] Synthesis, characterization and antimicrobial properties of Cobalt(III), Nickel(III), Copper(II) and Zinc(II) complexes with pyridine and thiocyanate
Abalintsina, Seth Armand
Conde, Mariam Asseng
Eni, Donatus Bekindaka
Agwara, Moise Ondoh
SCIENTIFIC AFRICAN, 2022, 18
[26] Synthesis, characterization, spectroscopic and theoretical studies of new zinc(II), copper(II) and nickel(II) complexes based on imine ligand containing 2-aminothiophenol moiety
Shafaatian, Bita
Mousavi, S. Sedighe
Afshari, Sadegh
JOURNAL OF MOLECULAR STRUCTURE, 2016, 1123 : 191 - 198
[27] Synthesis, characterization, antiproliferative of pyrimidine based ligand and its Ni(II) and Pd(II) complexes and effectiveness of electroporation
Alkis, Mehmet Esref
Buldurun, Kenan
Turan, Nevin
Alan, Yusuf
Yilmaz, Unzile Kelestemur
Mantarci, Asim
JOURNAL OF BIOMOLECULAR STRUCTURE & DYNAMICS, 2022, 40 (09) : 4073 - 4083
[28] Copper(II), nickel(II), and ruthenium(III) complexes of an oxopyrrolidine-based heterocyclic ligand as anticancer agents
Wani, Waseem A.
Al-Othman, Zeid
Ali, Imran
Saleem, Kishwar
Hsieh, Ming-Fa
JOURNAL OF COORDINATION CHEMISTRY, 2014, 67 (12) : 2110 - 2130
[29] Spectral characterization of a new cyclobutane and thiazole substituted Schiff base ligand and its Co(II), Cu(II), Ni(II), and Zn(II) complexes
Yilmaz, I
Çukurovali, A
SPECTROSCOPY LETTERS, 2004, 37 (01) : 59 - 72
[30] Copper(II) complexes with ONS donor ligand and triphenylphosphine: Synthesis, characterization and catalytic applications
Priyarega, S.
Tamizh, M. Muthu
Babu, S. Ganesh
Karvembu, R.
Natarajan, K.
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 2012, 51 (03): : 453 - 457

← 1 2 3 4 5 →