Precise synthesis of olefin block copolymers using a syndiospecific living polymerization system

被引：0

作者：

Zheng-guo Cai

Hai-hui Su

Takeshi Shiono

机构：

[1] Donghua University,State Key Lab for Modification of Chemical Fibers and Polymer Materials, College of Material Science and Engineering

[2] Hiroshima University,Graduate School of Engineering

来源：

Chinese Journal of Polymer Science | 2013年 / 31卷

关键词：

Single-site catalyst; Propylene; Norbornene; Living polymerization; Block copolymer;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

This feature article summarizes the synthesis of novel olefin block copolymers using fast syndiospecific living homo- and copolymerization of propylene, higher 1-alkene, and norbornene with ansa-fluorenylamidodimethyltitaniumbased catalyst according to the authors’ recent results. The catalytic synthesis of monodisperse polyolefin and olefin block copolymer was also described using this living system.

引用

页码：541 / 549

页数：8

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